Those greenish pictures we see in the movies and on TV come from night vision goggles (NVGs) or other devices that use the same core technologies. NVGs take in small amounts of visible light, magnify it greatly, and project that on a display.
Cameras made from NVG technology have the same limitations as the naked eye: if there isn’t enough visible light available, they can’t see well. The imaging performance of anything that relies on reflected light is limited by the amount and strength of the light being reflected.
NVG and other lowlight cameras are not very useful during twilight hours, when there is too much light for them to work effectively, but not enough light for you to see with the naked eye. Thermal cameras aren’t affected by visible light, so they can give you clear pictures even when you are looking into the setting sun. In fact, you can aim a spotlight at a FLIR and still get a perfect picture.